Toxicología ambiental y analítica

SOC Effects on Diethyl Phthalate Sorption to Four Soils in China

Abstract

Jiabin Wang, Yanhua Wu, Weilin Shi and Juan Gao

Purpose: Phthalate esters (PAEs) are commonly detected in agricultural soils of China, which can post potential threats to human health. Understanding their sorption to soils is important in assessing their transport and bioavailability in environment. Limited research focuses on the influence of soil organic carbon (SOC) on PAEs adsorption to soils at different depths and increased dissolved organic carbon (DOC) after adsorption. Materials and Methods: Batch sorption experiments of diethyl phthalate (DEP) to four types of soils were conducted in this study, including black soil, fluvo-aquic soil, paddy soil, and red soil. Total concentration of solute DEP and the concentration of free DEP not sorbed to DOC were measured with HPLC. The UV absorbance of supernatant was measured and specific UV absorbance at 254 nm was calculated for DOC aromaticity. Sorption isotherms of DEP to soil particles were fitted to the Langmuir model and the Freundlich model. Results and Discussion: Partial SOC can dissolve to DOC in solution, and 47.4- 89.4% of total DEP can be sorbed to DOC. Increasing DEP in solution can enhance aliphatic SOC dissolving. The sorption coefficients of DEP are higher to fluvo-aquic soils (Koc for surface soils 1820 L kg-1 and subsurface soils 1388 L kg-1) than to other soils (<520 L kg-1), which indicates that SOC fractions of different soils have varied affinity to DEP. Conclusions: SOC plays an important role in DEP sorption to soil particles. Soil samples from surface layers have higher affinity than those from subsurface layers. DOC from SOC in solution is important for DEP transport in soil, and organic pollution can accelerate SOC dissolving.